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1

C–C and C–N Couplings in Reactions of the Benzylidyne-Bridged Complex [Mo 2 Cp 2 (μ-CPh)(μ-PCy 2 )(CO) 2 ] with Small Unsaturated Organics

García, M. Esther, García-Vivó, Daniel, Menéndez, Sonia, Ruiz, Miguel A.

Journal:

Organometallics

Year:

2016

Language:

english

File:

PDF, 956 KB

english, 2016

2

Exploiting σ/π Coordination Isomerism to Prepare Homologous Organoalkali Metal (Li, Na, K) Monomers with Identical Ligand Sets

Prof. Matthew G. Davidson, Dr. Daniel Garcia-Vivo, Dr. Alan R. Kennedy, Prof. Robert E. Mulvey, Dr. Stuart D. Robertson

Journal:

Chemistry - A European Journal

Year:

2011

Language:

english

File:

PDF, 641 KB

english, 2011

3

Alkyne to carbyne coupling reactions of the unsaturated methoxycarbyne-bridged complex [Mo2(η5-C5H5)2(μ-COMe)(μ-PCy2)(CO)2]

M. Esther García, Daniel García-Vivó, Miguel A. Ruiz

Journal:

Journal of Organometallic Chemistry

Year:

2010

Language:

english

File:

PDF, 385 KB

english, 2010

4

Reactivity of the Phosphinidene-Bridged Complexes [Mo2Cp(μ-κ1:κ1,η5-PC5H4)(η6-1,3,5-C6H3tBu3)(CO)2] and [Mo2Cp2(μ-PH)(η6-1,3,5-C6H3tBu3)(CO)2] toward Alkynes: Multicomponent Reactions in the Presence of Ligands

Alvarez, M. Angeles, Amor, Inmaculada, García, M. Esther, García-Vivó, Daniel, Ruiz, Miguel A., Suárez, Jaime

Journal:

Organometallics

Year:

2012

Language:

english

File:

PDF, 1.08 MB

english, 2012

5

Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy and Methoxycarbyne Ligands. 1. Synthesis, Structure, and Bonding of 30-Electron Complexes

García, M. Esther, García-Vivó, Daniel, Ruiz, Miguel A., Alvarez, Santiago, Aullón, Gabriel

Journal:

Organometallics

Year:

2007

Language:

english

File:

PDF, 461 KB

english, 2007

6

Reactions of the Tetrafluoroborate Complex [Mo 2 Cp 2 (κ 2 -F 2 BF 2 )(μ-PPh 2 ) 2 (CO)]BF 4 with Mono- and Bidentate Ligands Having E–H bonds (E = O, S, Se, N, P)

Cimadevilla, Fernanda, García, M. Esther, García-Vivó, Daniel, Ruiz, Miguel A., Graiff, Claudia, Tiripicchio, Antonio

Journal:

Inorganic Chemistry

Year:

2012

Language:

english

File:

PDF, 613 KB

english, 2012

7

Reactions of the Unsaturated Hydroxo Complex [W 2 Cp 2 (OH)(μ-PPh 2 ) 2 (CO)]BF 4 with Mono- and Bidentate Ligands Having E–H bonds (E = O, S, N)

Cimadevilla, Fernanda, García, M. Esther, García-Vivó, Daniel, Ruiz, Miguel A., Graiff, Claudia, Tiripicchio, Antonio

Journal:

Inorganic Chemistry

Year:

2012

Language:

english

File:

PDF, 649 KB

english, 2012

8

Reactivity of the Anionic Diphosphorus Complex [Mo 2 Cp 2 (μ-PCy 2 )(CO) 2 (μ-κ 2 :κ 2 -P 2 )] − Toward ER 3 X Electrophiles (E = C to Pb): Insights into the Multisite Donor Ability and Dynamics of the P 2 Ligand

Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Ramos, Alberto, Ruiz, Miguel A.

Journal:

Inorganic Chemistry

Year:

2012

Language:

english

File:

PDF, 2.08 MB

english, 2012

9

Protonation reactions of the oxo complex cis-[Mo2(η5-C5H5)2(O)(μ-PPh2)2(CO)]. Hydroxo and tetrafluoroborate derivatives

Fernanda Cimadevilla, M. Esther García, Daniel García-Vivó, Miguel A. Ruiz, M. Teresa Rueda, Sabine Halut

Journal:

Journal of Organometallic Chemistry

Year:

2012

Language:

english

File:

PDF, 600 KB

english, 2012

10

Reversible P–C Coupling Reactions at the Unsaturated Dimolybdenum Carbyne Complex [Mo 2 (η 5 -C 5 H 5 ) 2 (CPh)(μ-PCy 2 )(μ-SPh)(CO)] +

Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Menéndez, Sonia, Ruiz, Miguel A.

Journal:

Organometallics

Year:

2012

Language:

english

File:

PDF, 1.10 MB

english, 2012

11

Electronic Structure and Reactivity of the Carbyne-Bridged Dimolybdenum Radical [Mo 2 (η 5 -C 5 H 5 ) 2 (μ-CPh)(μ-PCy 2 )(μ-CO)] +

Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Menéndez, Sonia, Ruiz, Miguel A.

Journal:

Organometallics

Year:

2013

Language:

english

File:

PDF, 1.93 MB

english, 2013

12

Dimolybdenum Cyclopentadienyl Complexes with Bridging Chalcogenophosphinidene Ligands

Alvarez, Belén, Alvarez, M. Angeles, Amor, Inmaculada, García, M. Esther, García-Vivó, Daniel, Suárez, Jaime, Ruiz, Miguel A.

Journal:

Inorganic Chemistry

Year:

2012

Language:

english

File:

PDF, 1.06 MB

english, 2012

13

Group 4 initiators for the stereoselective ROP of rac-β-butyrolactone and its copolymerization with rac-lactide

Jeffery, Ben J., Whitelaw, Emma L., Garcia-Vivo, Daniel, Stewart, Joseph A., Mahon, Mary F., Davidson, Matthew G., Jones, Matthew D.

Journal:

Chemical Communications

Year:

2011

Language:

english

File:

PDF, 1.30 MB

english, 2011

14

Hydrogen Atom Transfer Reactions of the Unsaturated Hydroxycarbyne Complex [W 2 Cp 2 (μ-COH)(μ-PPh 2 ) 2 ]BF 4

Cimadevilla, Fernanda, García, M. Esther, García-Vivó, Daniel, Ruiz, Miguel A., Graiff, Claudia, Tiripicchio, Antonio

Journal:

Organometallics

Year:

2013

Language:

english

File:

PDF, 1.04 MB

english, 2013

15

Insertion, Rearrangement, and Coupling Processes in the Reactions of the Unsaturated Hydride Complex [W 2 (η 5 -C 5 H 5 ) 2 (H)(μ-PCy 2 )(CO) 2 ] with Isocyanides

Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Ruiz, Miguel A., Vega, M. Fernanda

Journal:

Organometallics

Year:

2013

Language:

english

File:

PDF, 1.17 MB

english, 2013

16

Multisite Reactivity of the Unsaturated Methoxycarbyne Complex [Mo 2 (η 5 -C 5 H 5 ) 2 (µ-COMe)(µ-PCy 2 )(µ-CO)]

García-Vivó, Daniel, García, M. Esther, Ruiz, Miguel A.

Journal:

Organometallics

Year:

2008

Language:

english

File:

PDF, 105 KB

english, 2008

17

Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy and Methoxycarbyne Ligands. 3. Formation and Cleavage of C−C and C−O Bonds in the Reactions of the Complexes [Mo 2 Cp 2 (µ-COMe)(µ-COR)(µ-PCy 2 )]BF 4 (R = Me, Et)

García, M. Esther, García-Vivó, Daniel, Ruiz, Miguel A.

Journal:

Organometallics

Year:

2008

Language:

english

File:

PDF, 468 KB

english, 2008

18

Monomerizing Alkali-Metal 3,5-Dimethylbenzyl Salts with Tris( N , N -dimethyl-2-aminoethyl)amine (Me 6 TREN): Structural and Bonding Implications

Armstrong, David R., Davidson, Matthew G., Garcia-Vivo, Daniel, Kennedy, Alan R., Mulvey, Robert E., Robertson, Stuart D.

Journal:

Inorganic Chemistry

Year:

2013

Language:

english

File:

PDF, 2.86 MB

english, 2013

19

Thermally Induced Dehydrogenation of Amine-Borane Adducts and Ammonia-Borane by Group 6 Cyclopentadienyl Complexes Having Single and Triple Metal-Metal Bonds

García-Vivó, Daniel, Huergo, Estefanía, Ruiz, Miguel A., Travieso-Puente, Raquel

Journal:

European Journal of Inorganic Chemistry

Year:

2013

Language:

english

File:

PDF, 760 KB

english, 2013

20

Cyclopentadienyl and related complexes of the group 6 elements having metal–metal triple bonds: Synthesis, structure, bonding and reactivity

García-Vivó, Daniel, Ramos, Alberto, Ruiz, Miguel A.

Journal:

Coordination Chemistry Reviews

Year:

2013

Language:

english

File:

PDF, 6.04 MB

english, 2013

21

Reactions of the Unsaturated Ditungsten Complexes [W 2 Cp 2 (μ-PPh 2 ) 2 (CO) x ] ( x = 1, 2) with Nitric Oxide: Stereoselective Carbonyl Displacement and Oxygen-Transfer Reactions of a Nitrite Ligand

Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Melón, Sonia, Ruiz, Miguel A., Toyos, Adrián

Journal:

Inorganic Chemistry

Year:

2014

Language:

english

File:

PDF, 934 KB

english, 2014

22

Insertion, coupling and elimination processes in the reactions of the unsaturated alkyl-bridged complexes [Mo2(η5-C5H5)2(μ-CH2R)(μ-PCy2)(CO)2] (R = H, Ph) with isocyanides and secondary phosphines

Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Martínez, M. Eugenia, Ramos, Alberto, Ruiz, Miguel A.

Journal:

Dalton Transactions

Year:

2014

Language:

english

File:

PDF, 1008 KB

english, 2014

23

Reactivity of the Anionic Diphosphorus Complex [Mo 2 Cp 2 (μ-PCy 2 )(μ-κ 2 :κ 2 -P 2 )(CO) 2 ] − toward Phosphorus- and Transition Metal-Based Electrophiles

Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Lozano, Raquel, Ramos, Alberto, Ruiz, Miguel A.

Journal:

Inorganic Chemistry

Year:

2013

Language:

english

File:

PDF, 1.21 MB

english, 2013

24

Site-Selectivity in the Protonation and Related Reactions of Chalcogenophosphinidene-Bridged Dimolybdenum Cyclopentadienyl Complexes

Alvarez, Belén, Alvarez, M. Angeles, Amor, Inmaculada, García, M. Esther, García-Vivó, Daniel, Suárez, Jaime, Ruiz, Miguel A.

Journal:

European Journal of Inorganic Chemistry

Year:

2014

Language:

english

File:

PDF, 1.38 MB

english, 2014

25

Symmetrization in a Phosphinidene-Bridged Complex To Give a Diphosphanediyl Derivative with Metal-Centered Reactivity

Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Ramos, Alberto, Ruiz, Miguel A., Suárez, Jaime

Journal:

Inorganic Chemistry

Year:

2012

Language:

english

File:

PDF, 236 KB

english, 2012

26

Formation of P−H, P−C, and C−H Bonds by Hydride Attack on a Electrophilic Phosphide-Bridged Dimolybdenum Complex. Trapping the Phosphinidene Ligand with Borane

Amor, Inmaculada, García-Vivó, Daniel, García, M. Esther, Ruiz, Miguel A., Sáez, David, Hamidov, Hayrullo, Jeffery, John C.

Journal:

Organometallics

Year:

2007

Language:

english

File:

PDF, 89 KB

english, 2007

27

Carbene- and Carbyne-like Behavior of the Mo−P Multiple Bond in a Dimolybdenum Complex Inducing Trigonal-Pyramidal Coordination of a Phosphinidene Ligand

Alvarez, M. Angeles, Amor, Inmaculada, García, M. Esther, García-Vivó, Daniel, Ruiz, Miguel A.

Journal:

Inorganic Chemistry

Year:

2007

Language:

english

File:

PDF, 111 KB

english, 2007

28

Formation and Cleavage of C−C, C−O, and O−H Bonds Involving Methoxycarbyne and Hydroxycarbyne Ligands at Unsaturated Dimolybdenum Complexes

Alvarez, Celedonio M., Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Ruiz, Miguel A.

Journal:

Organometallics

Year:

2005

Language:

english

File:

PDF, 83 KB

english, 2005

29

Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy- and Methoxycarbyne Ligands. 2. Synthesis, Structure, and Bonding of 32- and 34-Electron Complexes §

García, M. Esther, García-Vivó, Daniel, Ruiz, Miguel A., Alvarez, Santiago, Aullón, Gabriel

Journal:

Organometallics

Year:

2007

Language:

english

File:

PDF, 409 KB

english, 2007

30

Activation of H–H and H–O Bonds at Phosphorus with Diiron Complexes Bearing Pyramidal Phosphinidene Ligands

Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Ramos, Alberto, Ruiz, Miguel A.

Journal:

Inorganic Chemistry

Year:

2012

Language:

english

File:

PDF, 1.08 MB

english, 2012

31

Tris(2-dimethylaminoethyl)amine: a simple new tripodal polyamine ligand for Group 1 metals

Cousins, David M., Davidson, Matthew G., Frankis, Catherine J., García-Vivó, Daniel, Mahon, Mary F.

Journal:

Dalton Transactions

Year:

2010

Language:

english

File:

PDF, 191 KB

english, 2010

32

Unprecedented participation of a four-coordinate hydrogen atom in the cubane core of lithium and sodium phenolates

Cousins, David M., Davidson, Matthew G., García-Vivó, Daniel

Journal:

Chemical Communications

Year:

2013

Language:

english

File:

PDF, 1.28 MB

english, 2013

33

Hydride, gold( i ) and related derivatives of the unsaturated ditungsten anion [W 2 Cp 2 (μ-PCy 2 )(μ-CO) 2 ] −

Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Ruiz, Miguel A., Vega, M. Fernanda

Journal:

Dalton Transactions

Year:

2014

Language:

english

File:

PDF, 783 KB

english, 2014

34

Well-controlled synthesis of boronic-acid functionalised poly(lactide)s: a versatile platform for biocompatible polymer conjugates and sensors

Cross, Alison J., Davidson, Matthew G., García-Vivó, Daniel, James, Tony D.

Journal:

Year:

2012

Language:

english

File:

PDF, 402 KB

english, 2012

35

Stepwise hydrogenation of an arylthiophosphinidene isocyanide complex to give tethered aldimine and aminocarbene functions

Alvarez, M. Angeles, Alvarez, Belén, García, M. Esther, García-Vivó, Daniel, Ruiz, Miguel A.

Journal:

Dalton Transactions

Year:

2013

Language:

english

File:

PDF, 530 KB

english, 2013

36

Nucleophilic behaviour of dioxo- and thiooxophosphorane complexes [MoCp(CO) 2 {E,P-EP(O)(2,4,6-C 6 H 2t Bu 3 )}] − (E = O, S)

Alonso, María, Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Ruiz, Miguel A.

Journal:

Dalton Transactions

Year:

2014

Language:

english

File:

PDF, 542 KB

english, 2014

37

Structural diversity in polyamine Lewis base stabilised lithium aryloxides

Cousins, David M., Davidson, Matthew G., García-Vivó, Daniel, Mahon, Mary F.

Journal:

Dalton Transactions

Year:

2010

Language:

english

File:

PDF, 326 KB

english, 2010

38

Mild P–P Bond Cleavage in the Methyldiphosphenyl Complex [Mo 2 Cp 2 (μ-PCy 2 )(μ-κ 2 :κ 2 -P 2 Me)(CO) 2 ] To Give Novel Phosphide-Bridged Trinuclear Derivatives

Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Lozano, Raquel, Ramos, Alberto, Ruiz, Miguel A.

Journal:

Inorganic Chemistry

Year:

2014

Language:

english

File:

PDF, 1.75 MB

english, 2014

39

Reactions of the Unsaturated Ditungsten Anion [W 2 Cp 2 (μ-PCy 2 )(μ-CO) 2 ] − with C- and P-Based Electrophiles

Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Ruiz, Miguel A., Vega, M. Fernanda

Journal:

Organometallics

Year:

2015

Language:

english

File:

PDF, 520 KB

english, 2015

40

Thermally Stable Diazoalkane Derivatives of the Unsaturated Ditungsten Hydride [W 2 Cp 2 (H)(μ-PCy 2 )(CO) 2 ]

Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Huergo, Estefanía, Ruiz, Miguel A., Vega, M. Fernanda

Journal:

Organometallics

Year:

2015

Language:

english

File:

PDF, 644 KB

english, 2015

41

Mild N–O Bond Cleavage Reactions of a Pyramidalized Nitrosyl Ligand Bridging a Dimolybdenum Center

Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Ruiz, Miguel A., Toyos, Adrián

Journal:

Inorganic Chemistry

Year:

2015

Language:

english

File:

PDF, 570 KB

english, 2015

42

Insertion and C–C coupling processes in reactions of the unsaturated hydride [W 2 Cp 2 (H)(μ-PCy 2 )(CO) 2 ] with alkynes

Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Ruiz, Miguel A., Vega, M. Fernanda

Journal:

Dalton Transactions

Year:

2016

Language:

english

File:

PDF, 1.40 MB

english, 2016

43

Electronic Structure and Multisite Basicity of the Pyramidal Phosphinidene-Bridged Dimolybdenum Complex [Mo 2 (η 5 -C 5 H 5 )(μ-κ 1 :κ 1 ,η 5 -PC 5 H 4 )(η 6 -C 6 H 3t Bu 3 )(CO) 2

Albuerne, Isabel G., Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Ruiz, Miguel A.

Journal:

Inorganic Chemistry

Year:

2015

Language:

english

File:

PDF, 1.63 MB

english, 2015

44

Synthesis and DFT Study of a Diphenylsilanone-Bridged Dimolybdenum Complex

Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Menéndez, Sonia, Ruiz, Miguel A.

Journal:

Chemistry - A European Journal

Year:

2016

Language:

english

File:

PDF, 754 KB

english, 2016

45

The doubly-bonded ditungsten anion [W 2 Cp 2 (μ-PPh 2 )(NO) 2 ] − : an entry to the chemistry of unsaturated nitrosyl complexes

Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Ruiz, Miguel A., Toyos, Adrián

Journal:

Dalton Transactions

Year:

2016

Language:

english

File:

PDF, 570 KB

english, 2016

46

Phosphinidene-bridged binuclear complexes

García, M. Esther, García-Vivó, Daniel, Ramos, Alberto, Ruiz, Miguel A.

Journal:

Coordination Chemistry Reviews

Year:

2017

Language:

english

File:

PDF, 7.76 MB

english, 2017

47

Cycloaddition Reactions of the Phosphinidene-Bridged Complex [Mo 2 Cp(μ-κ 1 :κ 1 ,η 5 -PC 5 H 4 )(CO) 2 (η 6 -HMes*)] with Diazoalkanes and Other Heterocumulenes

Albuerne, Isabel G., Alvarez, M. Angeles, Amor, Inmaculada, García, M. Esther, García-Vivó, Daniel, Ruiz, Miguel A.

Journal:

Inorganic Chemistry

Year:

2016

Language:

english

File:

PDF, 1.25 MB

english, 2016

48

Synthesis of the Unsaturated [MMoCp(µ-PR 2 )(CO) 5 ] - Anions (M = Mn, R = Ph; M = Re, R = Cy): Versatile Precursors of Heterometallic Complexes

Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Huergo, Estefanía, Ruiz, Miguel A.

Journal:

European Journal of Inorganic Chemistry

Year:

2017

Language:

english

File:

PDF, 1.63 MB

english, 2017

49

Chemistry of CS 2 - and SCNPh-adducts of the pyramidal phosphinidene-bridged complex [Mo 2 Cp(μ–κ 1 :κ 1 ,η 5 -PC 5 H 4 )(CO) 2 (η 6 -HMes*)(PMe 3 )]

Albuerne, Isabel G., Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Ruiz, Miguel A.

Journal:

Dalton Transactions

Year:

2017

Language:

english

File:

PDF, 1.06 MB

english, 2017

50

Divergent Reactivity of a Phosphinidene-Bridged Dimolybdenum Complex Toward 1-Alkynes: P–C, P–H, C–C, and C–H Couplings

García, M. Esther, García-Vivó, Daniel, Ruiz, Miguel A., Sáez, David

Journal:

Organometallics

Year:

2017

Language:

english

File:

PDF, 1.63 MB

english, 2017

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